Wednesday, June 17, 2009

Types Of Refinery

A refinery is a production facility composed of a group of chemical engineering unit processes and unit operations used for refining certain materials or converting raw material into products of value.



The various types of refineries include:

Oil refinery: Converts petroleum crude oil into high-octane motor fuel (gasoline/petrol), diesel oil, liquefied petroleum gases (LPG), jet aircraft fuel, kerosene, heating fuel oils, lubricating oils, asphalt and petroleum coke.

Sugar refinery: Converts sugar cane and sugar beets into crystallized sugar and sugar syrups.


Natural gas processing plant: Purifies and converts raw natural gas into residential, commercial and industrial fuel gas, and also recovers natural gas liquids (NGL) such as ethane, propane, butanes and pentanes.


Salt refinery: Cleans salt (NaCl), produced by the solar evaporation of sea water, followed by washing and re-crystallization.


Various metal refineries such as alumina, copper, gold, lead, nickel, silver, uranium, and zinc.


Vegetable oil refinery



A typical oil refinery

Oil refinery The image below is a schematic flow diagram of a typical oil refinery that depicts the various unit processes and the flow of intermediate product streams that occurs between the inlet crude oil feedstock and the final end products. The diagram depicts only one of the literally hundreds of different oil refinery configurations. It does not include any of the usual refinery facilities providing utilities such as steam, cooling water, and electric power as well as storage tanks for crude oil feedstock and for intermediate products and end products.

Electrical Generator

In electricity generation, an electrical generator is a device that converts mechanical energy to electrical energy, generally using electromagnetic induction. The reverse conversion of electrical energy into mechanical energy is done by a motor; motors and generators have many similarities. A generator forces electric charges to move through an external electrical circuit, but it does not create electricity or charge, which is already present in the wire of its windings. It is somewhat analogous to a water pump, which creates a flow of water but does not create the water inside. The source of mechanical energy may be a reciprocating or turbine steam engine, water falling through a turbine or waterwheel, an internal combustion engine, a wind turbine, a hand crank, compressed air or any other source of mechanical energy.

Historic developments.

Before the connection between magnetism and electricity was discovered, electrostatic generators were invented that used electrostatic principles. These generated very high voltages and low currents. They operated by using moving electrically charged belts, plates and disks to carry charge to a high potential electrode. The charge was generated using either of two mechanisms:

  • Electrostatic induction
  • The triboelectric effect

where the contact between two insulators leaves them charged.Because of their inefficiency and the difficulty of insulating machines producing very high voltages, electrostatic generators had low power ratings and were never used for generation of commercially-significant quantities of electric power. The Wimshurst machine and Van de Graaff generator are examples of these machines that have survived.

Desalter

A desalter is a process unit on an oil refinery that removes salt from the crude oil. The salt is dissolved in the water in the crude oil, not in the crude oil itself. The desalting is usually the first process in crude oil refining. The salt content after the desalter is usually measured in PTB - pounds of salt per thousand barrels of crude oil.[1] Another specification is Basic sediment and water.


The term desalter may also refer to a water desalination facility used to treat brackish water from agricultural runoff. This may be done either to produce potable water for human or animal consumption, or to reduce the salinity of river water prior to its crossing an international border, usually to comply with the terms of a treaty. Desalters are also used to treat groundwater reservoirs in areas impacted by cattle feedlots and dairies.

Why Desalt Crude?


The salts that are most frequently present in crude oil are Calcium,Sodium and Magnesium Chlorides. If these compounds are not removed from the oil several problems arise in the refining process. The high temperatures that occur downstream in the process could cause water hydrolysis, which in turn allows the formation of hydrochloric acid.Sand, Silts, Salt deposit and Foul Heat ExchangersWater Heat of Vaporization reduces crude Pre-Heat capacitySodium, Arsenic and Other Metals can poison CatalystsEnvironmental Compliance, i.e., By removing the suspended solids, which might otherwise become an issue in flue gas opacity norms, etc.,



Chemical reactor


In chemical engineering, chemical reactors are vessels designed to contain chemical reactions. The design of a chemical reactor deals with multiple aspects of chemical engineering. Chemical engineers design reactors to maximize net present value for the given reaction. Designers ensure that the reaction proceeds with the highest efficiency towards the desired output product, producing the highest yield of product while requiring the least amount of money to purchase and operate. Normal operating expenses include energy input, energy removal, raw material costs, labor, etc. Energy changes can come in the form of heating or cooling, pumping to increase pressure, frictional pressure loss (such as pressure drop across a 90o elbow or an orifice plate), agitation, etc.

There are two main basic vessel types:

  • a tank
  • a pipe

Both types can be used as continuous reactors or batch reactors. Most commonly, reactors are run at steady-state, but can also be operated in a transient state. When a reactor is first brought back into operation (after maintenance or inoperation) it would be considered to be in a transient state, where key process variables change with time. Both types of reactors may also accommodate one or more solids (reagents, catalyst, or inert materials), but the reagents and products are typically liquids and gases.


There are three main basic models used to estimate the most important process variables of different chemical reactors:

  • batch reactor model (batch),
  • continuous stirred-tank reactor model (CSTR),
  • plug flow reactor

model (PFR).Furthermore, catalytic reactors require separate treatment, whether they are batch, CST, or PF reactors, as the many assumptions of the simpler models are not valid.
Key process variables include

  • residence time (τ, lower case Greek tau)
  • volume (V)
  • temperature (T)
  • pressure (P)concentrations of chemical species (C1, C2, C3, ... Cn)
  • heat transfer coefficients (h, U)

Friday, June 12, 2009

Air preheater


An air preheater or air heater is a general term to describe any device designed to heat air before another process (for example, combustion in a boiler) with the primary objective of increasing the thermal efficiency of the process. They may be used alone or to replace a recuperative heat system or to replace a steam coil.
In particular, this article describes the combustion air preheaters used in large boilers found in thermal power stations producing electric power from e.g. fossil fuels, biomasses or waste.

The purpose of the air preheater is to recover the heat from the boiler flue gas which increases the thermal efficiency of the boiler by reducing the useful heat lost in the flue gas. As a consequence, the flue gases are also sent to the flue gas stack (or chimney) at a lower temperature, allowing simplified design of the ducting and the flue gas stack. It also allows control over the temperature of gases leaving the stack .

Turbine

A turbine is a rotary engine that extracts energy from a fluid flow. Claude Burdin (1788-1873) coined the term from the Latin turbo, or vortex, during an 1828 engineering competition. Benoit Fourneyron (1802-1867), a student of Claude Burdin, built the first practical water turbine.
The simplest turbines have one moving part, a rotor assembly, which is a shaft with blades attached. Moving fluid acts on the blades, or the blades react to the flow, so that they rotate and impart energy to the rotor. Early turbine examples are windmills and water wheels.
Gas, steam, and water turbines usually have a casing around the blades that contains and controls the working fluid. Credit for invention of the modern steam turbine is given to British Engineer Sir Charles Parsons (1854 - 1931).
A device similar to a turbine but operating in reverse is a compressor or pump. The axial compressor in many gas turbine engines is a common example.




Theory of operation



A working fluid contains potential energy (pressure head) and kinetic energy (velocity head). The fluid may be compressible or incompressible. Several physical principles are employed by turbines to collect this energy:


Impulse turbines


These turbines change the direction of flow of a high velocity fluid jet. The resulting impulse spins the turbine and leaves the fluid flow with diminished kinetic energy. There is no pressure change of the fluid in the turbine rotor blades. Before reaching the turbine the fluid's pressure head is changed to velocity head by accelerating the fluid with a nozzle. Pelton wheels and de Laval turbines use this process exclusively. Impulse turbines do not require a pressure casement around the runner since the fluid jet is prepared by a nozzle prior to reaching turbine. Newton's second law describes the transfer of energy for impulse turbines.


Reaction turbines


These turbines develop torque by reacting to the fluid's pressure or weight. The pressure of the fluid changes as it passes through the turbine rotor blades. A pressure casement is needed to contain the working fluid as it acts on the turbine stage(s) or the turbine must be fully immersed in the fluid flow (wind turbines). The casing contains and directs the working fluid and, for water turbines, maintains the suction imparted by the draft tube. Francis turbines and most steam turbines use this concept. For compressible working fluids, multiple turbine stages may be used to harness the expanding gas efficiently. Newton's third law describes the transfer of energy for reaction turbines.